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Issue 40, 2015
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Unprecedented formation of η4-(vinylketene)iron complexes from η4-(diene)iron complexes and aromatic compounds in the presence of a Lewis acid

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Abstract

A novel and unprecedented formation of η4-(vinylketene)iron complexes from η4-(diene)iron complexes is described herein. Treatment of η4-(diene)iron complexes with a Lewis acid such as GaCl3 or AlCl3 in the presence of aromatic compounds under a CO atmosphere affords η4-(vinylketene)iron complexes via electrophilic aromatic substitution.

Graphical abstract: Unprecedented formation of η4-(vinylketene)iron complexes from η4-(diene)iron complexes and aromatic compounds in the presence of a Lewis acid

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Article information


Submitted
30 Jan 2015
Accepted
06 Mar 2015
First published
06 Mar 2015

Chem. Commun., 2015,51, 8454-8456
Article type
Communication
Author version available

Unprecedented formation of η4-(vinylketene)iron complexes from η4-(diene)iron complexes and aromatic compounds in the presence of a Lewis acid

T. Okauchi, N. Sata, A. Urakawa and M. Kitamura, Chem. Commun., 2015, 51, 8454
DOI: 10.1039/C5CC00870K

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