Issue 27, 2015
From the journal:

Chemical Communications

Lewis-acid induced disaggregation of dimeric arylantimony oxides†

Ralf Kather,a   Tomáš Svoboda,ab   Maren Wehrhahn,a   Elena Rychagova,cd   Enno Lork,a   Libor Dostál,*b   Sergey Ketkov*cd  and  Jens Beckmann*a  

* Corresponding authors

a Institute of Inorganic Chemistry, Bremen University, Leobener Straße, 28359 Bremen, Germany
E-mail: j.beckmann@uni-bremen.de

b Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, CZ-532 10 Pardubice, Czech Republic
E-mail: Libor.Dostal@upce.cz

c G. A. Razuvaev Institute of Organometallic Chemistry RAS, 49 Tropinin St., 603950 Nizhny Novgorod, Russian Federation
E-mail: sketkov@iomc.ras.ru

d N. I. Lobachevsky Nizhny Novgorod State University, Gagarin ave. 23, 603950 Nizhny Novgorod, Russian Federation

Abstract

The previously known dimeric arylantimony oxides (Ph3SbO)2 and [2,6-(Me2NCH2)2C6H3SbO]2 were disaggregated by the Lewis acid B(C6F5)3 giving rise to the formation of the Lewis pair complexes Ph3SbOB(C6F5)3 and 2,6-(Me2NCH2)2C6H3SbOB(C6F5)3 having short bipolar single Sb–O bonds.

Graphical abstract: Lewis-acid induced disaggregation of dimeric arylantimony oxides

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Article information

DOI
https://doi.org/10.1039/C5CC00738K
Article type
Communication
Submitted
26 Jan 2015
Accepted
20 Feb 2015
First published
23 Feb 2015

Chem. Commun., 2015,51, 5932-5935

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Lewis-acid induced disaggregation of dimeric arylantimony oxides

R. Kather, T. Svoboda, M. Wehrhahn, E. Rychagova, E. Lork, L. Dostál, S. Ketkov and J. Beckmann, Chem. Commun., 2015, 51, 5932 DOI: 10.1039/C5CC00738K

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