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Issue 21, 2015
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Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes

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Abstract

Interaction of the reactive 14 VE {Ir(IBioxMe4)3}+ fragment with fluoroarenes results exclusively in ortho-C–H bond oxidative addition and formation of 16 VE Ir(III) derivatives [Ir(IBioxMe4)3(Ar)H]+ (Ar = 2-C6H4F, 2,3-C6H3F2, 2,4,6-C6H2F3). The C–H bond activation reactions occur under mild conditions and are reversible.

Graphical abstract: Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes

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Publication details

The article was received on 19 Jan 2015, accepted on 06 Feb 2015 and first published on 13 Feb 2015


Article type: Communication
DOI: 10.1039/C5CC00529A
Citation: Chem. Commun., 2015,51, 4425-4428
  • Open access: Creative Commons BY license
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    Low-coordinate iridium NHC complexes derived from selective and reversible C–H bond activation of fluoroarenes

    S. A. Hauser, I. Prokes and A. B. Chaplin, Chem. Commun., 2015, 51, 4425
    DOI: 10.1039/C5CC00529A

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