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Issue 27, 2015
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Rh(iii)-catalyzed and alcohol-involved carbenoid C–H insertion into N-phenoxyacetamides using α-diazomalonates

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Abstract

Here we report a new and mild Rh(III)-catalyzed and alcohol-involved carbenoid C–H insertion into N-phenoxyacetamides using α-diazomalonates. This reaction provided a straightforward way for installing both an α-quaternary carbon center and a free-OH moiety into the phenyl ring, thus giving access to useful 2-(2-hydroxyphenyl)-2-alkoxymalonates with good substrate/functional group tolerance.

Graphical abstract: Rh(iii)-catalyzed and alcohol-involved carbenoid C–H insertion into N-phenoxyacetamides using α-diazomalonates

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Article information


Submitted
14 Jan 2015
Accepted
04 Feb 2015
First published
05 Feb 2015

Chem. Commun., 2015,51, 5868-5871
Article type
Communication
Author version available

Rh(III)-catalyzed and alcohol-involved carbenoid C–H insertion into N-phenoxyacetamides using α-diazomalonates

J. Zhou, J. Shi, X. Liu, J. Jia, H. Song, H. E. Xu and W. Yi, Chem. Commun., 2015, 51, 5868
DOI: 10.1039/C5CC00354G

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