SCHEDULED MAINTENANCE
High molecular weight sugar poly(orthoesters) were synthesized through reverse anomeric effect (RAE). We demonstrated that when RAE-enabled promoters, such as 4-(dimethylamino)pyridine (DMAP), triphenylphosphine (TPP) or imidazole, were employed, efficient polymerizations were achieved, giving sugar poly(orthoesters) with molecular weights up to 18 kDa.
L. Li, J. Wang, M. Obrinske, I. Milligan, K. O'Hara, L. Bitterman and W. Du, Chem. Commun., 2015, 51, 6972 DOI: 10.1039/C5CC00332F
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