Jump to main content
Jump to site search

Issue 30, 2015
Previous Article Next Article

The aldimine effect in bis(imino)pyridine complexes: non-planar nickel(i) complexes of a bis(aldimino)pyridine ligand

Author affiliations

Abstract

Reduction of bis(aldimino)pyridine nickel(II) dihalide forms a non-planar bis(aldimino)pyridine nickel(I) halide. Unlike the previously reported square-planar bis(ketimino)pyridine nickel chloride, for which the spin density was localized on the ligand, the present species demonstrate Npy–Ni–X angles of 156°–162° and significant spin density at the metal inferred from EPR measurements and DFT calculations.

Graphical abstract: The aldimine effect in bis(imino)pyridine complexes: non-planar nickel(i) complexes of a bis(aldimino)pyridine ligand

Back to tab navigation

Supplementary files

Article information


Submitted
09 Jan 2015
Accepted
27 Jan 2015
First published
27 Jan 2015

Chem. Commun., 2015,51, 6496-6499
Article type
Communication
Author version available

The aldimine effect in bis(imino)pyridine complexes: non-planar nickel(I) complexes of a bis(aldimino)pyridine ligand

B. R. Reed, S. A. Stoian, R. L. Lord and S. Groysman, Chem. Commun., 2015, 51, 6496 DOI: 10.1039/C5CC00203F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.


Social activity

Search articles by author

Spotlight

Advertisements