Issue 32, 2015
From the journal:

Chemical Communications

Tackling poison and leach: catalysis by dangling thiol–palladium functions within a porous metal–organic solid†

Bo Gui,‡a   Ka-Kit Yee,‡b   Yan-Lung Wong,b   Shek-Man Yiu,b   Matthias Zeller,c   Cheng Wang*a  and  Zhengta Xu*b  

* Corresponding authors

a Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
E-mail: chengwang@whu.edu.cn

b Department of Biology and Chemistry, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong, China
E-mail: zhengtao@cityu.edu.hk

c Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, OH 44555, USA

Abstract

Self-standing thiol (−SH) groups within a Zr(IV)-based metal–organic framework (MOF) anchor Pd(II) atoms for catalytic applications: the spatial constraint prevents the thiol groups from sealing off/poisoning the Pd(II) center, while the strong Pd–S bond precludes Pd leaching, enabling multiple cycles of heterogeneous catalysis to be executed.

Graphical abstract: Tackling poison and leach: catalysis by dangling thiol–palladium functions within a porous metal–organic solid

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Article information

DOI
https://doi.org/10.1039/C5CC00140D
Article type
Communication
Submitted
07 Jan 2015
Accepted
26 Feb 2015
First published
27 Feb 2015

Chem. Commun., 2015,51, 6917-6920

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Tackling poison and leach: catalysis by dangling thiol–palladium functions within a porous metal–organic solid

B. Gui, K. Yee, Y. Wong, S. Yiu, M. Zeller, C. Wang and Z. Xu, Chem. Commun., 2015, 51, 6917 DOI: 10.1039/C5CC00140D

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