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Issue 30, 2015
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Synthesis and characterization of bis-triruthenium cluster derivatives of an all equatorial [60]fullerene tetramalonate

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Abstract

The reaction of the tetrakis[di(ethoxycarbonyl)methano]-C60 (1) with Ru3(CO)12 afforded the first bis-parallel C60–metal cluster complex: parallel-[Ru3(CO)9]23222-C60[C(COOC2H5)2]4}. The two triruthenium groups are found in either a parallel or a tilted orientation relative to each other, as determined by NMR. Only the parallel form was characterized by X-ray crystallography.

Graphical abstract: Synthesis and characterization of bis-triruthenium cluster derivatives of an all equatorial [60]fullerene tetramalonate

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Article information


Submitted
29 Dec 2014
Accepted
19 Jan 2015
First published
20 Jan 2015

Chem. Commun., 2015,51, 6489-6492
Article type
Communication
Author version available

Synthesis and characterization of bis-triruthenium cluster derivatives of an all equatorial [60]fullerene tetramalonate

C. Chen, A. Aghabali, C. Suarez, M. M. Olmstead, A. L. Balch and L. Echegoyen, Chem. Commun., 2015, 51, 6489
DOI: 10.1039/C4CC10397A

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