Issue 23, 2015
From the journal:

Chemical Communications

A simple access to transition metal cyclopropenylidene complexes†

Yannick D. Bidal,a   Mathieu Lesieur,a   Mohand Melaimi,b   David B. Cordes,a   Alexandra M. Z. Slawin,a   Guy Bertrand*b  and  Catherine S. J. Cazin*a  

* Corresponding authors

a EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, KY16 9ST, UK
E-mail: cc111@st-andrews.ac.uk

b UCSD-CNRS Joint Research Laboratory (UMI 3555), Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093-0343, USA

Abstract

We report the first example of BAC–Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au–, Pd–, Ir– and Rh–BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.

Graphical abstract: A simple access to transition metal cyclopropenylidene complexes

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Article information

DOI
https://doi.org/10.1039/C4CC10375K
Article type
Communication
Submitted
28 Dec 2014
Accepted
15 Jan 2015
First published
16 Jan 2015

Chem. Commun., 2015,51, 4778-4781

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A simple access to transition metal cyclopropenylidene complexes

Y. D. Bidal, M. Lesieur, M. Melaimi, D. B. Cordes, A. M. Z. Slawin, G. Bertrand and C. S. J. Cazin, Chem. Commun., 2015, 51, 4778 DOI: 10.1039/C4CC10375K

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