Jump to main content
Jump to site search

Issue 26, 2015
Previous Article Next Article

Asymmetric hydroamination catalyzed by a new chiral zirconium system: reaction scope and mechanism

Author affiliations

Abstract

A new class of chiral zirconium complexes supported by chiral tridentate [ONO]-type of ligands derived from amino acids were synthesized and structurally characterized. They catalyzed asymmetric hydroamination/cyclization of primary aminoalkenes to give five- and six-membered N-heterocyclic amines with up to 94% ee.

Graphical abstract: Asymmetric hydroamination catalyzed by a new chiral zirconium system: reaction scope and mechanism

Back to tab navigation

Supplementary files

Article information


Submitted
16 Dec 2014
Accepted
19 Feb 2015
First published
19 Feb 2015

This article is Open Access

Chem. Commun., 2015,51, 5751-5753
Article type
Communication

Asymmetric hydroamination catalyzed by a new chiral zirconium system: reaction scope and mechanism

X. Zhou, B. Wei, X. Sun, Y. Tang and Z. Xie, Chem. Commun., 2015, 51, 5751
DOI: 10.1039/C4CC10032H

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
  • For reproduction of material from PCCP:
    [Original citation] - Published by the PCCP Owner Societies.
  • For reproduction of material from PPS:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
  • For reproduction of material from all other RSC journals:
    [Original citation] - Published by The Royal Society of Chemistry.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.


Social activity

Search articles by author

Spotlight

Advertisements