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Issue 16, 2015
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Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides

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Abstract

A silver nitrate-mediated, efficient phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides was developed. This process provides a convenient route for the synthesis of a variety of 2-diarylphosphoryl benzothiazoles and thiazoles which are promising precursors of a series of hemilabile P,N-ligands with small bite angles.

Graphical abstract: Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides

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Publication details

The article was received on 16 Dec 2014, accepted on 20 Jan 2015 and first published on 28 Jan 2015


Article type: Communication
DOI: 10.1039/C4CC10017D
Chem. Commun., 2015,51, 3450-3453

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    Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides

    H. Zhang, W. Lin, Z. Wu, W. Ruan and T. Wen, Chem. Commun., 2015, 51, 3450
    DOI: 10.1039/C4CC10017D

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