Issue 27, 2015
From the journal:

Chemical Communications

Highly efficient regioselective hydrosilylation of allenes using a [(3IP)Pd(allyl)]OTf catalyst; first example of allene hydrosilylation with phenyl- and diphenylsilane†

Hosein Tafazoliana  and  Joseph A. R. Schmidt*a  

* Corresponding authors

a Department of Chemistry & Biochemistry, School of Green Chemistry and Engineering, College of Natural Sciences and Mathematics, The University of Toledo, 2801 W. Bancroft St. MS 602, Toledo, Ohio 43606-3390, USA
E-mail: Joseph.Schmidt@utoledo.edu
Fax: +1-419-530-4033
Tel: +1-419-530-1512

Abstract

A [(3IP)Pd(allyl)]OTf complex was shown to function efficiently and regioselectively in allene hydrosilylation with phenyl- and diphenylsilane. The catalyst also proved to be highly active for allene hydrosilylation employing a wide range of silanes, each of which produced a single regioisomer.

Graphical abstract: Highly efficient regioselective hydrosilylation of allenes using a [(3IP)Pd(allyl)]OTf catalyst; first example of allene hydrosilylation with phenyl- and diphenylsilane

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Article information

DOI
https://doi.org/10.1039/C4CC09804H
Article type
Communication
Submitted
08 Dec 2014
Accepted
26 Feb 2015
First published
26 Feb 2015

Chem. Commun., 2015,51, 5943-5946

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Highly efficient regioselective hydrosilylation of allenes using a [(3IP)Pd(allyl)]OTf catalyst; first example of allene hydrosilylation with phenyl- and diphenylsilane

H. Tafazolian and J. A. R. Schmidt, Chem. Commun., 2015, 51, 5943 DOI: 10.1039/C4CC09804H

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