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Issue 12, 2015
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Asymmetric Kita spirolactonisation catalysed by anti-dimethanoanthracene-based iodoarenes

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Abstract

Enantiopure C2-symmetric iodoarenes based on the rigid all-carbon anti-dimethanoanthracene framework are shown to catalyse the asymmetric oxidative Kita spirolactonisation of propanoic acid-tethered 1-naphthols with significant levels of asymmetric induction of up to 67% ee.

Graphical abstract: Asymmetric Kita spirolactonisation catalysed by anti-dimethanoanthracene-based iodoarenes

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Publication details

The article was received on 05 Dec 2014, accepted on 20 Dec 2014 and first published on 22 Dec 2014


Article type: Communication
DOI: 10.1039/C4CC09724F
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Chem. Commun., 2015,51, 2376-2379

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    Asymmetric Kita spirolactonisation catalysed by anti-dimethanoanthracene-based iodoarenes

    S. J. Murray and H. Ibrahim, Chem. Commun., 2015, 51, 2376
    DOI: 10.1039/C4CC09724F

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