Issue 20, 2015
From the journal:

Chemical Communications

Microporous polymer network films covalently bound to gold electrodes†

Daniel Becker,‡a   Nina Heidary,‡bc   Marius Horch,b   Ulrich Gernert,d   Ingo Zebger,b   Johannes Schmidt,a   Anna Fischer*bc  and  Arne Thomas*a  

* Corresponding authors

a Department of Chemistry, Functional Materials, Technische Universität Berlin, Hardenbergstr. 40, 10623 Berlin, Germany
E-mail: arne.thomas@tu-berlin.de

b Department of Chemistry, Technische Universität Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany

c Universität Freiburg, Institut für Anorganische und Analytische Chemie, Albertstrasse 21, 79104 Freiburg, Germany
E-mail: anna.fischer@ac.uni-freiburg.de

d Center for Electron Microscopy (ZELMI), Technische Universität Berlin, Strasse des 17. Juni 135, 10623 Berlin, Germany

Abstract

Covalent attachment of a microporous polymer network (MPN) on a gold surface is presented. A functional bromophenyl-based self-assembled monolayer (SAM) formed on the gold surface acts as co-monomer in the polymerisation of the MPN yielding homogeneous and robust coatings. Covalent binding of the films to the electrode is confirmed by SEIRAS measurements.

Graphical abstract: Microporous polymer network films covalently bound to gold electrodes

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Article information

DOI
https://doi.org/10.1039/C4CC09637A
Article type
Communication
Submitted
02 Dec 2014
Accepted
05 Feb 2015
First published
05 Feb 2015

Chem. Commun., 2015,51, 4283-4286

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Microporous polymer network films covalently bound to gold electrodes

D. Becker, N. Heidary, M. Horch, U. Gernert, I. Zebger, J. Schmidt, A. Fischer and A. Thomas, Chem. Commun., 2015, 51, 4283 DOI: 10.1039/C4CC09637A

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