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Issue 14, 2015
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Extended π-conjugated ruthenium zinc–porphyrin complexes with enhanced nonlinear-optical properties

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Abstract

Zinc porphyrin dimers and trimers, in which the porphyrins are connected via a ruthenium metal core, exhibit large third-order nonlinear optical absorption coefficients and refractive indices. These properties are a result of the presence of multiple porphyrins, which lead to an extension of the π-conjugated system and the octupolar effect.

Graphical abstract: Extended π-conjugated ruthenium zinc–porphyrin complexes with enhanced nonlinear-optical properties

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Publication details

The article was received on 01 Dec 2014, accepted on 03 Jan 2015 and first published on 05 Jan 2015


Article type: Communication
DOI: 10.1039/C4CC09592H
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Chem. Commun., 2015,51, 2855-2858

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    Extended π-conjugated ruthenium zinc–porphyrin complexes with enhanced nonlinear-optical properties

    M. de Torres, S. Semin, I. Razdolski, J. Xu, J. A. A. W. Elemans, T. Rasing, A. E. Rowan and R. J. M. Nolte, Chem. Commun., 2015, 51, 2855
    DOI: 10.1039/C4CC09592H

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