Issue 14, 2015
From the journal:

Chemical Communications

Extended π-conjugated ruthenium zinc–porphyrin complexes with enhanced nonlinear-optical properties†

Miriam de Torres,*a   Sergey Semin,a   Ilya Razdolski,a   Jialiang Xu,*a   Johannes A. A. W. Elemans,a   Theo Rasing,a   Alan E. Rowana  and  Roeland J. M. Noltea  

* Corresponding authors

a Institute for Molecules and Materials (IMM), Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ Nijmegen, the Netherlands
E-mail: mrmtorresdmg@hotmail.com, J.Xu@science.ru.nl

Abstract

Zinc porphyrin dimers and trimers, in which the porphyrins are connected via a ruthenium metal core, exhibit large third-order nonlinear optical absorption coefficients and refractive indices. These properties are a result of the presence of multiple porphyrins, which lead to an extension of the π-conjugated system and the octupolar effect.

Graphical abstract: Extended π-conjugated ruthenium zinc–porphyrin complexes with enhanced nonlinear-optical properties

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Article information

DOI
https://doi.org/10.1039/C4CC09592H
Article type
Communication
Submitted
01 Dec 2014
Accepted
03 Jan 2015
First published
05 Jan 2015

Chem. Commun., 2015,51, 2855-2858

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Extended π-conjugated ruthenium zinc–porphyrin complexes with enhanced nonlinear-optical properties

M. de Torres, S. Semin, I. Razdolski, J. Xu, J. A. A. W. Elemans, T. Rasing, A. E. Rowan and R. J. M. Nolte, Chem. Commun., 2015, 51, 2855 DOI: 10.1039/C4CC09592H

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