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Issue 30, 2015
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Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker

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Abstract

The first tritopic carborane-based linker, H3BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal–organic framework (MOF), NU-700 (Cu3(BCA)2). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m2 g−1.

Graphical abstract: Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker

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Article information


Submitted
18 Nov 2014
Accepted
22 Feb 2015
First published
13 Mar 2015

Chem. Commun., 2015,51, 6521-6523
Article type
Communication

Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker

D. J. Clingerman, W. Morris, J. E. Mondloch, R. D. Kennedy, A. A. Sarjeant, C. Stern, J. T. Hupp, O. K. Farha and C. A. Mirkin, Chem. Commun., 2015, 51, 6521
DOI: 10.1039/C4CC09212K

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