Jump to main content
Jump to site search

Issue 30, 2015
Previous Article Next Article

Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker

Author affiliations

Abstract

The first tritopic carborane-based linker, H3BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal–organic framework (MOF), NU-700 (Cu3(BCA)2). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m2 g−1.

Graphical abstract: Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker

Back to tab navigation

Supplementary files

Publication details

The article was received on 18 Nov 2014, accepted on 22 Feb 2015 and first published on 13 Mar 2015


Article type: Communication
DOI: 10.1039/C4CC09212K
Chem. Commun., 2015,51, 6521-6523

  •   Request permissions

    Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker

    D. J. Clingerman, W. Morris, J. E. Mondloch, R. D. Kennedy, A. A. Sarjeant, C. Stern, J. T. Hupp, O. K. Farha and C. A. Mirkin, Chem. Commun., 2015, 51, 6521
    DOI: 10.1039/C4CC09212K

Search articles by author

Spotlight

Advertisements