Issue 14, 2015
From the journal:

Chemical Communications

Caught! Crystal trapping of a side-on peroxo bound to Cr(iv)†

David P. de Sousa, ORCID logo a   Jennifer O. Bigelow,b   Jonas Sundberg,a   Lawrence Que, Jr.b  and  Christine J. McKenzie*a  

* Corresponding authors

a Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, 5230 Odense M, Denmark
E-mail: mckenzie@sdu.dk
Fax: +45 6615 8760
Tel: +45 6550 2518

b Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, Minnesota, USA

Abstract

A Cr(IV)η2–peroxo complex crystallizes from 33% aqueous H2O2. The complex is a likely intermediate in catalytic disproportionation of H2O2 proposed to occur through a single metal site mechanism in solution – and solid state.

Graphical abstract: Caught! Crystal trapping of a side-on peroxo bound to Cr(iv)

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Article information

DOI
https://doi.org/10.1039/C4CC08785B
Article type
Communication
Submitted
06 Nov 2014
Accepted
07 Jan 2015
First published
07 Jan 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 2802-2805

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Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

D. P. de Sousa, J. O. Bigelow, J. Sundberg, L. Que and C. J. McKenzie, Chem. Commun., 2015, 51, 2802 DOI: 10.1039/C4CC08785B

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