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Issue 25, 2015
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Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

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Abstract

A Ni(II) complex degrades electrochemically in the presence of acid in acetonitrile to form an electrode adsorbed film that catalytically evolves hydrogen. Comparison with a similar compound permitted investigation of the degradation mechanism.

Graphical abstract: Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

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Supplementary files

Article information


Submitted
31 Oct 2014
Accepted
24 Nov 2014
First published
04 Dec 2014

This article is Open Access

Chem. Commun., 2015,51, 5290-5293
Article type
Communication

Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

D. J. Martin, B. D. McCarthy, C. L. Donley and J. L. Dempsey, Chem. Commun., 2015, 51, 5290
DOI: 10.1039/C4CC08662G

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