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Issue 25, 2015
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Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes

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Abstract

An iron-mediated hydro-trifluoromethylthiolation of unactivated olefins under mild conditions was described for the first time. The reaction occurred to full conversion within 30 min at 0 °C and tolerates a variety of functional groups. Preliminary mechanistic studies suggested that the reaction proceeds via a free-radical pathway.

Graphical abstract: Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes

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Supplementary files

Article information


Submitted
31 Oct 2014
Accepted
26 Nov 2014
First published
26 Nov 2014

Chem. Commun., 2015,51, 5479-5481
Article type
Communication

Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes

T. Yang, L. Lu and Q. Shen, Chem. Commun., 2015, 51, 5479
DOI: 10.1039/C4CC08655D

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