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Issue 25, 2015
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IMes-acac: hybrid combination of diaminocarbene and acetylacetonato sub-units into a new anionic ambidentate NHC ligand

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Abstract

The mesoionic 5-acetylimidazolium-4-olate serves as precursor for an anionic, hybrid NHC, “IMes-acac”, consisting of fused diaminocarbene and acetylacetonato units, whose respective coordination abilities are evaluated by the formation of a series of representative copper(I) complexes illustrating the ambidentate character of the ligand.

Graphical abstract: IMes-acac: hybrid combination of diaminocarbene and acetylacetonato sub-units into a new anionic ambidentate NHC ligand

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Article information


Submitted
31 Oct 2014
Accepted
26 Nov 2014
First published
27 Nov 2014

Chem. Commun., 2015,51, 5271-5274
Article type
Communication

IMes-acac: hybrid combination of diaminocarbene and acetylacetonato sub-units into a new anionic ambidentate NHC ligand

V. César, V. Mallardo, A. Nano, G. Dahm, N. Lugan, G. Lavigne and S. Bellemin-Laponnaz, Chem. Commun., 2015, 51, 5271
DOI: 10.1039/C4CC08641D

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