Metal-free cascade construction of C–C bonds by activation of inert C(sp3)–H bonds

Honglin Zhang; Changduo Pan; Ning Jin; Zhangxi Gu; Hongwen Hu; Chengjian Zhu

doi:10.1039/C4CC08629E

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Metal-free cascade construction of C–C bonds by activation of inert C(sp³)–H bonds†

Honglin Zhang,^a Changduo Pan,^a Ning Jin,^a Zhangxi Gu,^a Hongwen Hu^a and Chengjian Zhu*^ab

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China
E-mail: cjzhu@nju.edu.cn

^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai, P. R. China

Abstract

A new synthetic strategy for C–C bond formation has been developed via a free radical cascade process under metal-free conditions. Activation of inert C(sp³)–H/elimination of SO₂/C–C bond formation were achieved in sequence in this system.

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Article information

DOI: https://doi.org/10.1039/C4CC08629E
Article type: Communication
Submitted: 31 Oct 2014
Accepted: 24 Nov 2014
First published: 25 Nov 2014

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Chem. Commun., 2015,51, 1320-1322

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Metal-free cascade construction of C–C bonds by activation of inert C(sp³)–H bonds

H. Zhang, C. Pan, N. Jin, Z. Gu, H. Hu and C. Zhu, Chem. Commun., 2015, 51, 1320 DOI: 10.1039/C4CC08629E

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