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Issue 8, 2015

Formation of ring-in-ring complexes between crown ethers and rigid TVBox8+

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Abstract

A rigid octacationic tetraviologen-based cyclophane, TVBox8+, is reported. It possesses a highly electron-deficient rectangular cavity with a length of 23 Å and width of 6.1 Å and is capable of encapsulating either two small π-aromatic guest molecules, such as PhMe and PhCl, simultaneously, or one large molecule, e.g., bis-1,5-dinaphtho[50]crown-14.

Graphical abstract: Formation of ring-in-ring complexes between crown ethers and rigid TVBox8+

Supplementary files

Article information


Submitted
12 Oct 2014
Accepted
25 Nov 2014
First published
26 Nov 2014

Chem. Commun., 2015,51, 1432-1435
Article type
Communication
Author version available

Formation of ring-in-ring complexes between crown ethers and rigid TVBox8+

J. Sun, M. Frasconi, Z. Liu, J. C. Barnes, Y. Wang, D. Chen, C. L. Stern and J. Fraser Stoddart, Chem. Commun., 2015, 51, 1432 DOI: 10.1039/C4CC08053J

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