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Issue 1, 2015
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Fluoride, bifluoride and trifluoromethyl complexes of iridium(i) and rhodium(i)

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Abstract

Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed.

Graphical abstract: Fluoride, bifluoride and trifluoromethyl complexes of iridium(i) and rhodium(i)

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The article was received on 01 Oct 2014, accepted on 27 Oct 2014 and first published on 27 Oct 2014


Article type: Communication
DOI: 10.1039/C4CC07772E
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Chem. Commun., 2015,51, 62-65

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    Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)

    B. J. Truscott, F. Nahra, A. M. Z. Slawin, D. B. Cordes and S. P. Nolan, Chem. Commun., 2015, 51, 62
    DOI: 10.1039/C4CC07772E

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