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Issue 6, 2015
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Anomalous self-reduction of layered double hydroxide (LDH): from α-Ni(OH)2 to hexagonal close packing (HCP) Ni/NiO by annealing without a reductant

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Abstract

The traditional concept that nickel layered double hydroxide (Ni LDH, also known as α-Ni(OH)2) converts to NiO after annealing has been taken without doubt and utilized to fabricate NiO for years. This work reports that an anomalous self-reduction phenomenon can occur for Ni LDH synthesized from an ionic liquid system.

Graphical abstract: Anomalous self-reduction of layered double hydroxide (LDH): from α-Ni(OH)2 to hexagonal close packing (HCP) Ni/NiO by annealing without a reductant

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Article information


Submitted
01 Oct 2014
Accepted
27 Oct 2014
First published
27 Oct 2014

Chem. Commun., 2015,51, 1004-1007
Article type
Communication

Anomalous self-reduction of layered double hydroxide (LDH): from α-Ni(OH)2 to hexagonal close packing (HCP) Ni/NiO by annealing without a reductant

X. Ge, C. D. Gu, X. L. Wang and J. P. Tu, Chem. Commun., 2015, 51, 1004
DOI: 10.1039/C4CC07767A

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