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Issue 25, 2015
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Visible-light-induced chemoselective reductive decarboxylative alkynylation under biomolecule-compatible conditions

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Abstract

We report a visible-light-induced reductive decarboxylative C(sp3)–C(sp) bond coupling reaction to construct aryl, alkyl and silyl substituted alkynes at room temperature in organic solvents or neutral aqueous solutions. This chemoselective alkynylation was compatible with various functional groups and biomolecules, and did not affect the protein enzyme activity.

Graphical abstract: Visible-light-induced chemoselective reductive decarboxylative alkynylation under biomolecule-compatible conditions

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Article information


Submitted
13 Aug 2014
Accepted
22 Sep 2014
First published
03 Oct 2014

Chem. Commun., 2015,51, 5275-5278
Article type
Communication

Visible-light-induced chemoselective reductive decarboxylative alkynylation under biomolecule-compatible conditions

J. Yang, J. Zhang, L. Qi, C. Hu and Y. Chen, Chem. Commun., 2015, 51, 5275
DOI: 10.1039/C4CC06344A

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