Mo(CO)6 catalysed chemoselective hydrosilylation of α,β-unsaturated amides for the formation of allylamines

Alexey Volkov; Fredrik Tinnis; Tove Slagbrand; Ida Pershagen; Hans Adolfsson

doi:10.1039/C4CC07150F

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Mo(CO)₆ catalysed chemoselective hydrosilylation of α,β-unsaturated amides for the formation of allylamines†

Alexey Volkov,^a Fredrik Tinnis,*^a Tove Slagbrand,^a Ida Pershagen^a and Hans Adolfsson*^a

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* Corresponding authors

^a Department of Organic Chemistry, Arrhenius Laboratory Stockholm University, SE-106 91, Stockholm, Sweden
E-mail: tinnis@organ.su.se, hansa@organ.su.se
Fax: +46-8-154908

Abstract

Molybdenum hexacarbonyl (Mo(CO)₆) was used as an efficient catalyst for the chemoselective reduction of the amide functionality in α,β-unsaturated compounds, under hydrosilylation conditions using 1,1,3,3-tetramethyldisiloxane (TMDS) as the hydride source.

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Article information

DOI: https://doi.org/10.1039/C4CC07150F
Article type: Communication
Submitted: 10 Sep 2014
Accepted: 27 Sep 2014
First published: 29 Sep 2014

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Chem. Commun., 2014,50, 14508-14511

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Mo(CO)₆ catalysed chemoselective hydrosilylation of α,β-unsaturated amides for the formation of allylamines

A. Volkov, F. Tinnis, T. Slagbrand, I. Pershagen and H. Adolfsson, Chem. Commun., 2014, 50, 14508 DOI: 10.1039/C4CC07150F

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