Issue 86, 2014
From the journal:

Chemical Communications

A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states†

Irene C. Cai, ORCID logo ‡a   Michael I. Lipschutz‡a  and  T. Don Tilley*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, CA 94720-1460, USA
E-mail: tdtilley@berkeley.edu

Abstract

The amido ligand –N(SiiPr3)DIPP (DIPP = 2,6-diisopropylphenyl) has been used to prepare two-coordinate complexes of CrI, CrII, and CrIII. The two-coordinate CrII complex has also been used to prepare a three-coordinate CrIII iodide complex, which can be used to access a stable CrIII methyl species.

Graphical abstract: A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states

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Article information

DOI
https://doi.org/10.1039/C4CC06615D
Article type
Communication
Submitted
22 Aug 2014
Accepted
08 Sep 2014
First published
09 Sep 2014

Chem. Commun., 2014,50, 13062-13065

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A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states

I. C. Cai, M. I. Lipschutz and T. D. Tilley, Chem. Commun., 2014, 50, 13062 DOI: 10.1039/C4CC06615D

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