Issue 91, 2014
From the journal:

Chemical Communications

Chiral metal phosphate catalysis: highly asymmetric hetero-Diels–Alder reactions†

Tao Liang,a   Guilong Li,a   Lukasz Wojtasb  and  Jon C. Antilla*a  

* Corresponding authors

a Department of Chemistry, University of South Florida, Tampa, Florida, USA
E-mail: jantilla@usf.edu

b Department of Chemistry X-ray Facility, University of South Florida, Tampa, Florida 33620, USA

Abstract

We report a highly enantioselective hetero-Diels–Alder reaction of α-keto esters and isatins catalyzed by chiral calcium BINOL-derived phosphates. The structure of the catalyst is detailed by X-ray crystal structure analysis.

Graphical abstract: Chiral metal phosphate catalysis: highly asymmetric hetero-Diels–Alder reactions

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Article information

DOI
https://doi.org/10.1039/C4CC06520D
Article type
Communication
Submitted
19 Aug 2014
Accepted
24 Sep 2014
First published
06 Oct 2014

Chem. Commun., 2014,50, 14187-14190

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Chiral metal phosphate catalysis: highly asymmetric hetero-Diels–Alder reactions

T. Liang, G. Li, L. Wojtas and J. C. Antilla, Chem. Commun., 2014, 50, 14187 DOI: 10.1039/C4CC06520D

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