Issue 88, 2014
From the journal:

Chemical Communications

Mn(ii)/O2-promoted oxidative annulation of vinyl isocyanides with boronic acids: synthesis of multi-substituted isoquinolines†

Hao Wang,a   Yang Yu,a   Xiaohu Honga  and  Bin Xu*abc  

* Corresponding authors

a Department of Chemistry, Innovative Drug Research Center, Shanghai University, Shanghai 200444, China
E-mail: xubin@shu.edu.cn
Fax: +86-21-66132830
Tel: +86-21-66132830

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

c Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China

Abstract

An efficient manganese(II)/O2-promoted oxidative radical cascade reaction was developed for the modular synthesis of multi-substituted isoquinolines from easily accessible vinyl isocyanides and boronic acids.

Graphical abstract: Mn(ii)/O2-promoted oxidative annulation of vinyl isocyanides with boronic acids: synthesis of multi-substituted isoquinolines

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Article information

DOI
https://doi.org/10.1039/C4CC06427E
Article type
Communication
Submitted
15 Aug 2014
Accepted
09 Sep 2014
First published
10 Sep 2014

Chem. Commun., 2014,50, 13485-13488

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Mn(II)/O2-promoted oxidative annulation of vinyl isocyanides with boronic acids: synthesis of multi-substituted isoquinolines

H. Wang, Y. Yu, X. Hong and B. Xu, Chem. Commun., 2014, 50, 13485 DOI: 10.1039/C4CC06427E

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