Fluorinated microporous organic polymers: design and applications in CO2 adsorption and conversion

Zhen-Zhen Yang; Yanfei Zhao; Hongye Zhang; Bo Yu; Zhishuang Ma; Guipeng Ji; Zhimin Liu

doi:10.1039/C4CC06423B

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Fluorinated microporous organic polymers: design and applications in CO₂ adsorption and conversion†

Zhen-Zhen Yang,^a Yanfei Zhao,^a Hongye Zhang,^a Bo Yu,^a Zhishuang Ma,^a Guipeng Ji^a and Zhimin Liu*^a

Author affiliations

* Corresponding authors

^a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: liuzm@iccas.ac.cn

Abstract

Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO₂ adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO₂ with propargyl alcohols to form α-alkylidene cyclic carbonates at 25 °C.

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Article information

DOI: https://doi.org/10.1039/C4CC06423B
Article type: Communication
Submitted: 15 Aug 2014
Accepted: 16 Sep 2014
First published: 16 Sep 2014

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Chem. Commun., 2014,50, 13910-13913

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Fluorinated microporous organic polymers: design and applications in CO₂ adsorption and conversion

Z. Yang, Y. Zhao, H. Zhang, B. Yu, Z. Ma, G. Ji and Z. Liu, Chem. Commun., 2014, 50, 13910 DOI: 10.1039/C4CC06423B

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