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Issue 87, 2014

Unprecedented formation of polycyclic diazadiborepine derivatives through cage deboronation of m-carborane

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Abstract

An unprecedented deboronation reaction of icosahedral carboranes is described, in which a BH group of m-carborane is detached from the cage and incorporated into an unusual nido-carborane-anellated diazadiborepine ring system.

Graphical abstract: Unprecedented formation of polycyclic diazadiborepine derivatives through cage deboronation of m-carborane

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Article information


Submitted
16 Aug 2014
Accepted
10 Sep 2014
First published
10 Sep 2014

This article is Open Access

Chem. Commun., 2014,50, 13239-13242
Article type
Communication
Author version available

Unprecedented formation of polycyclic diazadiborepine derivatives through cage deboronation of m-carborane

N. Harmgarth, C. G. Hrib, V. Lorenz, L. Hilfert and F. T. Edelmann, Chem. Commun., 2014, 50, 13239 DOI: 10.1039/C4CC06261B

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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