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Issue 92, 2014
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Direct carboxylation of simple arenes with CO2 through a rhodium-catalyzed C–H bond activation

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Abstract

Direct carboxylation of simple arenes under atmospheric pressure of CO2 is achieved through a rhodium-catalyzed C–H bond activation without the assistance of a directing group. Various arenes such as benzene, toluene, xylene, electron-rich or electron-deficient benzene derivatives, and heteroaromatics are directly carboxylated with high TONs.

Graphical abstract: Direct carboxylation of simple arenes with CO2 through a rhodium-catalyzed C–H bond activation

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Article information


Submitted
07 Aug 2014
Accepted
23 Sep 2014
First published
23 Sep 2014

Chem. Commun., 2014,50, 14360-14363
Article type
Communication
Author version available

Direct carboxylation of simple arenes with CO2 through a rhodium-catalyzed C–H bond activation

T. Suga, H. Mizuno, J. Takaya and N. Iwasawa, Chem. Commun., 2014, 50, 14360
DOI: 10.1039/C4CC06188H

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