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Issue 88, 2014
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A bimodal anionic MOF: turn-off sensing of CuII and specific sensitization of EuIII

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Abstract

A novel porous anionic MOF {[Mg3(ndc)2.5(HCO2)2(H2O)][NH2Me2]·2H2O·DMF} (1) having exchangeable dimethyl amine cations in 1D channels has been synthesized and characterized. Through cation exchange, 1 manifests bimodal functionality, being a turn-off sensor of CuII on one hand, and a selective sensitizer of EuIII emitting intense pure red emission on the other.

Graphical abstract: A bimodal anionic MOF: turn-off sensing of CuII and specific sensitization of EuIII

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Supplementary files

Article information


Submitted
31 Jul 2014
Accepted
09 Sep 2014
First published
10 Sep 2014

Chem. Commun., 2014,50, 13567-13570
Article type
Communication
Author version available

A bimodal anionic MOF: turn-off sensing of CuII and specific sensitization of EuIII

S. Bhattacharyya, A. Chakraborty, K. Jayaramulu, A. Hazra and T. K. Maji, Chem. Commun., 2014, 50, 13567
DOI: 10.1039/C4CC05991C

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