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Issue 89, 2014
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A 2D azine-linked covalent organic framework for gas storage applications

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Abstract

A new azine-linked covalent organic framework, ACOF-1, was synthesized by condensation of hydrazine hydrate and 1,3,5-triformylbenzene under solvothermal conditions. ACOF-1 has a high surface area and a small pore size, and it can store up to 177 mg g−1 of CO2, 9.9 mg g−1 of H2, and 11.5 mg g−1 of CH4, at 273 K and 1 bar, with high selectivity towards CO2 over N2 and CH4.

Graphical abstract: A 2D azine-linked covalent organic framework for gas storage applications

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Publication details

The article was received on 22 Jul 2014, accepted on 18 Sep 2014 and first published on 18 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC05665E
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Citation: Chem. Commun., 2014,50, 13825-13828
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    A 2D azine-linked covalent organic framework for gas storage applications

    Z. Li, X. Feng, Y. Zou, Y. Zhang, H. Xia, X. Liu and Y. Mu, Chem. Commun., 2014, 50, 13825
    DOI: 10.1039/C4CC05665E

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