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Issue 84, 2014
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Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks

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Abstract

The metalloligand [Ni(pedt)2] (pedt = 1-(pyridine-4-yl)ethylene-1,2-dithiolate) has been incorporated into two multi-dimensional structures for the first time. These coordination frameworks represent highly unusual interpenetration isomers and exhibit solid state redox and optical properties that reflect the electronically delocalised nature of the metalloligand.

Graphical abstract: Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks

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Article information


Submitted
15 Jul 2014
Accepted
04 Sep 2014
First published
05 Sep 2014

This article is Open Access

Chem. Commun., 2014,50, 12772-12774
Article type
Communication

Highly unusual interpenetration isomers of electroactive nickel bis(dithiolene) coordination frameworks

T. B. Faust, P. M. Usov, D. M. D'Alessandro and C. J. Kepert, Chem. Commun., 2014, 50, 12772
DOI: 10.1039/C4CC05438E

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