Cyclic ethers to esters and monoesters to bis-esters with unconventional coupling partners under metal free conditions via sp3 C–H functionalisation

Ganesh Majji; Srimanta Guin; Saroj K. Rout; Ahalya Behera; Bhisma K. Patel

doi:10.1039/C4CC05050A

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Cyclic ethers to esters and monoesters to bis-esters with unconventional coupling partners under metal free conditions via sp³ C–H functionalisation†‡

Ganesh Majji,^a Srimanta Guin,^a Saroj K. Rout,^a Ahalya Behera^a and Bhisma K. Patel*^a

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^a Department of Chemistry, Indian Institute of Technology Guwahati, Assam, India
E-mail: patel@iitg.ernet.in
Fax: +91-3612690762

Abstract

An efficient metal free oxidative esterification of sp³ C–H bonds (adjacent to an oxygen atom) in simple solvents like 1,4-dioxane, tetrahydropyran, tetrahydrofuran and ethyl acetate has been achieved using terminal aryl alkenes and alkynes as the ArCOO⁻ sources.

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Article information

DOI: https://doi.org/10.1039/C4CC05050A
Article type: Communication
Submitted: 02 Jul 2014
Accepted: 13 Aug 2014
First published: 13 Aug 2014

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Chem. Commun., 2014,50, 12193-12196

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Cyclic ethers to esters and monoesters to bis-esters with unconventional coupling partners under metal free conditions via sp³ C–H functionalisation

G. Majji, S. Guin, S. K. Rout, A. Behera and B. K. Patel, Chem. Commun., 2014, 50, 12193 DOI: 10.1039/C4CC05050A

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