A metal free domino synthesis of 3-aroylindoles via two sp3 C–H activation

Anupal Gogoi; Anju Modi; Srimanta Guin; Saroj Kumar Rout; Debapratim Das; Bhisma K. Patel

doi:10.1039/C4CC04407J

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A metal free domino synthesis of 3-aroylindoles via two sp³ C–H activation†

Anupal Gogoi,^a Anju Modi,^a Srimanta Guin,^a Saroj Kumar Rout,^a Debapratim Das^a and Bhisma K. Patel*^a

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^a Department of Chemistry, Indian Institute of Technology Guwahati, Assam, India
E-mail: patel@iitg.ernet.in
Fax: +91-3612690762

Abstract

A metal free synthesis of 3-aroylindole involving two sp³ C–H activation has been achieved starting from o-alkynyl-N,N-dialkylamines using catalyst TBAI and oxidant TBHP.

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DOI: https://doi.org/10.1039/C4CC04407J
Article type: Communication
Submitted: 10 Jun 2014
Accepted: 18 Jul 2014
First published: 21 Jul 2014

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Chem. Commun., 2014,50, 10445-10447

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A metal free domino synthesis of 3-aroylindoles via two sp³ C–H activation

A. Gogoi, A. Modi, S. Guin, S. K. Rout, D. Das and B. K. Patel, Chem. Commun., 2014, 50, 10445 DOI: 10.1039/C4CC04407J

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