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Issue 72, 2014
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Potential-driven molecular tiling of a charged polycyclic aromatic compound

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Abstract

Using in situ electrochemical scanning tunnelling microscopy (EC-STM), we demonstrate fully reversible tuning of molecular tiling between self-assembled structures with supramolecular motifs containing 2, 3, 4, 6 or 7 tectons. The structures can be explained by electrocompression of the cationic adlayer at the solid–liquid interface.

Graphical abstract: Potential-driven molecular tiling of a charged polycyclic aromatic compound

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Article information


Submitted
01 Jun 2014
Accepted
11 Jul 2014
First published
31 Jul 2014

Chem. Commun., 2014,50, 10376-10378
Article type
Communication

Potential-driven molecular tiling of a charged polycyclic aromatic compound

K. Cui, O. Ivasenko, K. S. Mali, D. Wu, X. Feng, K. Müllen, S. De Feyter and S. F. L. Mertens, Chem. Commun., 2014, 50, 10376
DOI: 10.1039/C4CC04189E

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