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Issue 79, 2014
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Gas-phase synthesis and reactivity of Cu+–benzyne complexes

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Abstract

Cu+–benzyne complexes bearing bidentate nitrogen ligands were synthesized in the gas phase for the first time using electrospray ionization mass spectrometry. The addition reactivity of copper-stabilized benzyne with amines was studied in the ion trap analyzer. The structures of products were identified by comparing their MSn data with authentic compounds obtained from another generation route.

Graphical abstract: Gas-phase synthesis and reactivity of Cu+–benzyne complexes

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Publication details

The article was received on 31 May 2014, accepted on 07 Aug 2014 and first published on 07 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC04168B
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Chem. Commun., 2014,50, 11668-11671

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    Gas-phase synthesis and reactivity of Cu+–benzyne complexes

    Y. Chai, S. Shen, G. Weng and Y. Pan, Chem. Commun., 2014, 50, 11668
    DOI: 10.1039/C4CC04168B

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