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Issue 72, 2014
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A molecular “screw-clamp”: accelerating click reactions in miniemulsions

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Abstract

The interface as a “screw clamp”: the copper-free 1,3-dipolar azide–alkyne cycloaddition at the interface of nanodroplets in miniemulsions was studied in detail by NMR spectroscopic methods. The reaction at the oil–water interface proved to exhibit higher rate constants, increased molecular weights and high regioregularity compared to the reaction in solution.

Graphical abstract: A molecular “screw-clamp”: accelerating click reactions in miniemulsions

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Supplementary files

Article information


Submitted
29 May 2014
Accepted
17 Jul 2014
First published
17 Jul 2014

This article is Open Access

Chem. Commun., 2014,50, 10495-10498
Article type
Communication
Author version available

A molecular “screw-clamp”: accelerating click reactions in miniemulsions

E. M. Alexandrino, P. Buchold, M. Wagner, A. Fuchs, A. Kreyes, C. K. Weiss, K. Landfester and F. R. Wurm, Chem. Commun., 2014, 50, 10495
DOI: 10.1039/C4CC04119D

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