Issue 67, 2014
From the journal:

Chemical Communications

Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination†

Bin Feng,‡ab   Hong-Gang Cheng,‡ab   Jia-Rong Chen,*ab   Qiao-Hui Deng,ab   Liang-Qiu Luab  and  Wen-Jing Xiao*ab  

* Corresponding authors

a Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan, Hubei 430079, China
E-mail: chenjiarong@mail.ccnu.edu.cn, wxiao@mail.ccnu.edu.cn
Fax: +86 27 67862041
Tel: +86 27 67862041

b Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), China

Abstract

The Pd/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination with a wide range of O- and N-nucleophiles have been developed (up to 97% yield, 98.5% ee). The products can also be conveniently transformed into biologically active chiral heterocycles.

Graphical abstract: Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination

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Article information

DOI
https://doi.org/10.1039/C4CC03920C
Article type
Communication
Submitted
22 May 2014
Accepted
04 Jul 2014
First published
04 Jul 2014

Chem. Commun., 2014,50, 9550-9553

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Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination

B. Feng, H. Cheng, J. Chen, Q. Deng, L. Lu and W. Xiao, Chem. Commun., 2014, 50, 9550 DOI: 10.1039/C4CC03920C

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