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Issue 66, 2014
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4-Halogeno-sydnones for fast strain promoted cycloaddition with bicyclo-[6.1.0]-nonyne

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Abstract

New sydnone derivatives have been synthesized and screened for their capacity to undergo fast copper-free cycloaddition reaction with bicyclo-[6.1.0]-nonyne. The influences of substitution in positions N-3 and C-4 of sydnones have been particularly studied leading to the identification of highly reactive partners for bio-orthogonal ligation reactions.

Graphical abstract: 4-Halogeno-sydnones for fast strain promoted cycloaddition with bicyclo-[6.1.0]-nonyne

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Publication details

The article was received on 19 May 2014, accepted on 13 Jun 2014 and first published on 30 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC03816A
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Chem. Commun., 2014,50, 9376-9378

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    4-Halogeno-sydnones for fast strain promoted cycloaddition with bicyclo-[6.1.0]-nonyne

    L. Plougastel, O. Koniev, S. Specklin, E. Decuypere, C. Créminon, D. Buisson, A. Wagner, S. Kolodych and F. Taran, Chem. Commun., 2014, 50, 9376
    DOI: 10.1039/C4CC03816A

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