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Issue 69, 2014
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A metal-free dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of organoboronic acids

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Abstract

The first example of a dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of catalytic amounts of Selectfluor and DABCO was reported, which provides a facile access to organoboronates. This reaction represents an unprecedented dyotropic rearrangement consisting of cleavage of two vicinal bonds (one C–C bond and one C[double bond, length as m-dash]C bond).

Graphical abstract: A metal-free dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of organoboronic acids

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Publication details

The article was received on 07 May 2014, accepted on 03 Jul 2014 and first published on 08 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC03450C
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Chem. Commun., 2014,50, 9879-9882

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    A metal-free dyotropic-like rearrangement of 2-oxa allylic alcohols in the presence of organoboronic acids

    W. Ye, W. Li and J. Zhang, Chem. Commun., 2014, 50, 9879
    DOI: 10.1039/C4CC03450C

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