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Issue 61, 2014
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Nanovalve activation by surface-attached photoacids

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Abstract

Proton transfer caused by excitation of a photoacid attached to the surface of a mesoporous silica nanoparticle activates a nanovalve and causes release of trapped molecules. The protonation of an aniline-based stalk releases a noncovalently bound cyclodextrin molecule that blocked a pore. The results show that pH-responsive molecular delivery systems can be externally controlled using light.

Graphical abstract: Nanovalve activation by surface-attached photoacids

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Publication details

The article was received on 03 May 2014, accepted on 05 Jun 2014 and first published on 05 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC03293D
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Citation: Chem. Commun., 2014,50, 8388-8390
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    Nanovalve activation by surface-attached photoacids

    T. M. Guardado-Alvarez, M. M. Russell and J. I. Zink, Chem. Commun., 2014, 50, 8388
    DOI: 10.1039/C4CC03293D

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