Issue 75, 2014
From the journal:

Chemical Communications

A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M–R to vanadate oxo†

Mu-Jeng Cheng,a   Robert J. Nielsen*a  and  William A. Goddard IIIa  

* Corresponding authors

a Materials and Process Simulation Center (139-74), California Institute of Technology, Pasadena, CA 91125, USA
E-mail: smith@wag.caltech.edu
Fax: +1 626 585 0918
Tel: +1 626 395 8140

Abstract

A new mechanism for generating C–O bonds from metal-hydrocarbyls involving homolytic, intermolecular migration of the hydrocarbyl group to a vanadium oxo is reported. Responsible for the C–O bond in phenol formed by the reaction of OVCl3 with HgPh2, it may provide air-regenerable metal oxos a role in aerobic alkane oxidations.

Graphical abstract: A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M–R to vanadate oxo

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Article information

DOI
https://doi.org/10.1039/C4CC03067B
Article type
Communication
Submitted
24 Apr 2014
Accepted
28 Jul 2014
First published
28 Jul 2014

Chem. Commun., 2014,50, 10994-10996

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A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M–R to vanadate oxo

M. Cheng, R. J. Nielsen and W. A. Goddard III, Chem. Commun., 2014, 50, 10994 DOI: 10.1039/C4CC03067B

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