Issue 61, 2014
From the journal:

Chemical Communications

Pd-Catalyzed C–H activation/oxidative cyclization of acetanilide with norbornene: concise access to functionalized indolines†

Yang Gao,a   Yubing Huang,a   Wanqing Wu,*a   Kefan Huanga  and  Huanfeng Jiang*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
E-mail: jianghf@scut.edu.cn, cewuwq@scut.edu.cn
Fax: +86 20-87112906
Tel: +86 20-87112906

Abstract

An efficient Pd-catalyzed oxidative cyclization reaction for the synthesis of functionalized indolines by direct C–H activation of acetanilide has been developed. The norbornylpalladium species formed via direct ortho C–H activation of acetanilides is supposed to be a key intermediate in this transformation.

Graphical abstract: Pd-Catalyzed C–H activation/oxidative cyclization of acetanilide with norbornene: concise access to functionalized indolines

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Article information

DOI
https://doi.org/10.1039/C4CC03062A
Article type
Communication
Submitted
24 Apr 2014
Accepted
02 Jun 2014
First published
18 Jun 2014

Chem. Commun., 2014,50, 8370-8373

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Pd-Catalyzed C–H activation/oxidative cyclization of acetanilide with norbornene: concise access to functionalized indolines

Y. Gao, Y. Huang, W. Wu, K. Huang and H. Jiang, Chem. Commun., 2014, 50, 8370 DOI: 10.1039/C4CC03062A

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