From ionic-liquid@metal–organic framework composites to heteroatom-decorated large-surface area carbons: superior CO2 and H2 uptake

Abstract

For the first time, high surface area uniformly nitrogen (N)- and boron-nitrogen (BN)-decorated nanoporous carbons have been successfully fabricated by impregnation of ionic liquids (ILs) within a metal–organic framework (MOF), MIL-100(Al), followed by carbonization, which exhibit remarkable CO₂ and H₂ adsorption capacities.