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Issue 57, 2014
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Copper-catalysed oxidative Csp3–H methylenation to terminal olefins using DMF

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Abstract

A copper-catalysed direct oxidative Csp3–H methylenation to terminal olefins using DMF as one carbon source was developed. In this reaction, various functional groups were well tolerated, thus providing a simple way to construct arylvinylketones and arylvinylpyridines. The preliminary mechanistic investigations revealed that CH2 was from DMF (N–CH3).

Graphical abstract: Copper-catalysed oxidative Csp3–H methylenation to terminal olefins using DMF

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Article information


Submitted
27 Mar 2014
Accepted
20 May 2014
First published
21 May 2014

Chem. Commun., 2014,50, 7636-7638
Article type
Communication
Author version available

Copper-catalysed oxidative Csp3–H methylenation to terminal olefins using DMF

J. Liu, H. Yi, X. Zhang, C. Liu, R. Liu, G. Zhang and A. Lei, Chem. Commun., 2014, 50, 7636
DOI: 10.1039/C4CC02275K

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