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Issue 57, 2014
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Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration

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Abstract

A novel radical phosphinylation of α,α-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of α-aryl-β-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)–C(sp3) and C(sp3)–P bonds was observed.

Graphical abstract: Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration

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Publication details

The article was received on 21 Mar 2014, accepted on 20 May 2014 and first published on 22 May 2014


Article type: Communication
DOI: 10.1039/C4CC02114B
Chem. Commun., 2014,50, 7642-7645

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    Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration

    X. Chu, Y. Zi, H. Meng, X. Xu and S. Ji, Chem. Commun., 2014, 50, 7642
    DOI: 10.1039/C4CC02114B

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