Issue 57, 2014
From the journal:

Chemical Communications

Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration†

Xue-Qiang Chu,a   You Zi,a   Hua Meng,a   Xiao-Ping Xu*a  and  Shun-Jun Ji*a  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, People's Republic of China
E-mail: xuxp@suda.edu.cn, shunjun@suda.edu.cn
Fax: +86-512-65880307
Tel: +86-512-65880307

Abstract

A novel radical phosphinylation of α,α-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of α-aryl-β-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)–C(sp3) and C(sp3)–P bonds was observed.

Graphical abstract: Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration

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Article information

DOI
https://doi.org/10.1039/C4CC02114B
Article type
Communication
Submitted
21 Mar 2014
Accepted
20 May 2014
First published
22 May 2014

Chem. Commun., 2014,50, 7642-7645

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Radical phosphinylation of α,α-diaryl allylic alcohols with concomitant 1,2-aryl migration

X. Chu, Y. Zi, H. Meng, X. Xu and S. Ji, Chem. Commun., 2014, 50, 7642 DOI: 10.1039/C4CC02114B

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