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Issue 78, 2014
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Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

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Abstract

We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO2 molecules, which is found to provide high CO2 storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

Graphical abstract: Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

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Article information


Submitted
21 Mar 2014
Accepted
29 May 2014
First published
29 May 2014

This article is Open Access

Chem. Commun., 2014,50, 11476-11479
Article type
Communication

Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

S. Muromachi, K. A. Udachin, K. Shin, S. Alavi, I. L. Moudrakovski, R. Ohmura and J. A. Ripmeester, Chem. Commun., 2014, 50, 11476
DOI: 10.1039/C4CC02111H

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